Beilstein J. Org. Chem.2020,16, 2026–2031, doi:10.3762/bjoc.16.169
phenyliodine diacetate (PIDA) and phenyliodine bis(trifluoroacetate) (PIFA), have been utilized for oxidative dimerization reactions [14][15]. The use of these one-electron oxidants, as well as non-metallic reagents, plays an important role in accessing symmetrical and asymmetricalbiaryls and polyaryls [1
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Graphical Abstract
Figure 1:
Selected natural products synthesized via oxidative dimerization.
Beilstein J. Org. Chem.2014,10, 1107–1113, doi:10.3762/bjoc.10.109
, electron-neutral and electron-donating substituents are reacted under the catalytic system furnishing unsymmetrical biaryl products in isolated yields of up to 96% in only 10 minutes.
Keywords: aryl bromide; 2-aryl-1,3-dihydro-1H-benzo[d]1,3,2-diazaborole; asymmetricalbiaryls; microwave; Suzuki–Miyaura
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Graphical Abstract
Figure 1:
Structures of organoboron compounds 1–3.